Design, Synthesis, and Characterization of Tetracationic Iodonium Macrocycles

Carré-Burrit, Asa and Goffinett, Quinton and Goodwin, A. W. and Huffman, Spencer and Surta, Todd and Collins , Dr. William R. (2013) Design, Synthesis, and Characterization of Tetracationic Iodonium Macrocycles. [Abstract]

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Abstract

The design and synthesis of mechanically interlocked molecules (e.g., catenated molecular structures) represents a unique challenge to the synthetic chemist. Central to this effort is the chemical generation of shape persistent molecular architectures. In particular, tetracationic iodonium macrocyclic structures have been experimentally shown to contain near perfect rectilinear geometries, making them potentially useful scaffolds for intermolecular catenation reactions. Our current efforts have focused on the expedient synthetic preparation of tetracationic iodonium macrocycles of various sizes. The successful synthesis of the bisphenylene-based macrocycle has allowed for initial studies into dynamic covalent catenation.

Item Type: Abstract
Created by Student or Faculty: Student
Additional Information: 8th Annual Natural & Behavioral Sciences Undergraduate Research Symposium Program
Uncontrolled Keywords: Catenated molecular structures, mechanically interlocked molecules, Tetracationic Iodonium Macrocycles, shape persistent molecular architectures
Subjects: School of Natural and Behavioral Sciences > Chemistry
NBS Symposium
Depositing User: Alejandro Marquez
Date Deposited: 10 May 2013 13:51
Last Modified: 10 May 2013 13:51
URI: http://eprints.fortlewis.edu/id/eprint/222


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