C-H Insertion of Diazoglycines – A Novel Approach to Unnatural Amino Acids

Dillard, Shannon and Miller , Dr. Kenneth A. (2012) C-H Insertion of Diazoglycines – A Novel Approach to Unnatural Amino Acids. [Abstract]

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Abstract

Metal carbenoids are useful intermediates capable of highly enantioselective C-H activations and cyclopropanation reactions among others. However, diazo compounds such as diazo glycines possessing a flanking nitrogen atom, apart from nitro groups, have not been reported. Progress toward the challenging synthesis of diazoglycines will be reported. A number of synthetic approaches particularly with regard to introduction of the diazo function were screened. The results of these experiments will be presented

Item Type: Abstract
Created by Student or Faculty: Student
Additional Information: 7th Annual Natural & Behavioral Sciences Undergraduate Research Symposium Program
Uncontrolled Keywords: Metal carbenoids, Enantioselective C-H activations, Cyclopropanation reactions, Diazo compounds, Diazo glycines possessing, Diazoglycines, Diazo function, Amino acids
Subjects: School of Natural and Behavioral Sciences > Chemistry
NBS Symposium
Depositing User: Alejandro Marquez
Date Deposited: 10 May 2013 12:58
Last Modified: 10 May 2013 12:58
URI: http://eprints.fortlewis.edu/id/eprint/282


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